Quantum Physics

Sunday, June 19, 2005

Ultraviolet catastrophe

The Ultraviolet Catastrophe (sometimes known as Rayleigh-Jeans Catastrophe) suggested that when an ideal black body reached a "thermal equilibrium" will probablt radiation radiation with infinate energy. This was later proven wrong, the solution to this catastrophe led to the outbreak of new physics.
The ultraviolet catastrophe results from the equipartition theorem of "classical statistical mechanics", which states that all modes (degrees of freedom) of a system at equilibrium have an average energy of kT / 2. According to classical electromagnetism, the number of electromagnetic modes in a 3-dimensional cavity, per unit frequency, is proportional to the square of the frequency.
Therefore, this implies that the radiated power per unit frequency should follow the Rayleigh-Jeans law, and be proportional to frequency squared. Thus, both the power at a given frequency and the total radiated power go to infinity as higher and higher frequencies are considered: this is clearly an impossibility, a point that was made independently by Einstein and by Lord Rayleigh and Sir James Jeans in the year 1905. Einstein pointed out that the difficulty could be avoided by making use of a hypothesis put forward five years earlier by Max Planck. Planck had postulated that electromagnetic energy did not follow the classical description, but could only oscillate or be emitted in discrete packets of energy proportional to the frequency (as given by Planck's law). This has the effect of reducing the number of possible modes with a given energy at high frequencies in the cavity described above, and thus the average energy at those frequencies by application of the equipartition theorem. The radiated power eventually goes to zero at infinite frequencies, and the total predicted power is finite. The formula for the radiated power for the idealized system (black body) was in line with known experiments, and came to be called Planck's law of black body radiation.

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